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Acids and Bases
Titanium(IV) chloride 208566-200G
Availablity:
In stock
Catalog/Part Number:
208566-200G
Brand:
MERCK
Supplier:
MERCK
Supplier Location:
GERMANY
Inventory Weight:
unavailable
Unit of Measurement:
Inventory Brochure:
unavailable
Catalog/Part Number:: 208566-200G
₦142,680.00
Description
General
description
Titanium(IV) chloride participates in the Baylis-Hillman
reaction of arylaldehydes with methyl vinyl ketone.[2] Neutral
solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the
addition of magnesium oxide as a base) have been used for the synthesis of
nanosized titanium dioxide.[3]
Application
Activates pyrrolidines for improved conversion, via a modified
Bouveault reaction, to the corresponding α,α-dimethylamines.[1]
Along with sodium borohydride, it forms an effective reagent for
the reduction of:[7]
• carboxylic acid and acyl chloride to alcohols
• carboxamides, oximes and lactams to amines
• sulfoxides to sulfides
Titanium(IV) chloride (TiCl4) has been used as a
precursor for the synthesis of Ag-TiO2@polyethylene glycol
(PEG) nanoparticles.[6] TiCl4 may also be used
as one of the constituents to synthesize TiO2/Al2O3 binary oxide
materials[4] and N-(10-oxo-vinylanthracen-9
Packaging
1.5 kg in Sure/Seal™
200 g in Sure/Seal™
Legal
Information
ReagentPlus is a registered
trademark of Sigma-Aldrich Co. LLC
Technical Specifications
Related Categories |
Acids, Acids & Bases, Alternative Energy, Catalysis and Inorganic Chemistry, Catalysts, |
| More... | |
| grade | ReagentPlus® |
| vapor pressure | 50 mmHg ( 55 °C) |
| 9.6 mmHg ( 20 °C) | |
| assay | 99.9% trace metals basis |
| form | liquid |
| bp | 135-136 °C (lit.) |
| mp | −25 °C (lit.) |
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