Proton-sponge® - 10G
Catalog/Part Number:: 158496-10G
₦73,080.00
Description
99%
Synonym: 1,8-Bis(dimethylamino)naphthalene, N,N,N′,N′-Tetramethyl-1,8-naphthalenediamine
CAS Number 20734-58-1
Linear Formula C10H6[N(CH3)2]2
Molecular Weight 214.31
General description
Proton-sponge is also referred as 1,8-dimethylamino naphthalene. It is very strong base with weak nucleophilic character due to steric effects. It also participates in the reactions between arachno-6,9-C2B8H14 and selected acyl chlorides. It has been tested as an effective H+ scavenger.
Application
Proton-sponge can be used in the synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds.[1] It was also used in the preparation of saturated fluoroalkyl(hydrido) complexes of Iridium.
Very strong base with weak nucleophilic character due to steric effects.
Packaging
10, 50 g in glass bottle
Safety Information
Symbol GHS07
Signal word Warning
Hazard statements H315-H319-H335
Precautionary statements P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, GlovesRIDADR NONH for all modes of transport
WGK Germany 3
Flash Point(F) 235.4 °F
Flash Point(C) 113 °C
Technical Specifications
Properties
Related Categories Acids & Bases, Bases, Building Blocks, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks,
assay 99%
mp 49-51 °C (lit.)
solubility chloroform: soluble 50 mg/mL, clear, faintly yellow to greenish-yellow
SMILES string CN(C)c1cccc2cccc(N(C)C)c12
InChI 1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
InChI key GJFNRSDCSTVPCJ-UHFFFAOYSA-N
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